synthesis, crystal structure and catalytic activity of a 1d chained ca(ii) coordination polymer with 3,5-bis(4-pyridylmethoxy)benzoate ligand

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ID: 153517
2017
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Abstract
A new 1D chained Ca(II) coordination polymer—namely, [CaL2(H2O)2]n (HL = 3,5-bis(4-pyridylmethoxy)benzoic acid)—was synthesized though the reaction of Ca(ClO4)2·4H2O, 3,5-bis(4-pyridylmethoxy)benzoic acid and NaOH in H2O/CH3CH2OH (v:v = 1:2) solution. Its structure was determined by elemental analysis, infrared spectrum, and single-crystal XRD. Structural analyses show that each Ca(II) ion is eight-coordinated by six oxygen atoms of four 3,5-bis(4-pyridylmethoxy)benzoate ligands and two oxygen atoms of two coordinated H2O molecules to form a square-antiprismatic CaO8 polyhedron. The Ca(II) complex displays a 1D chained structure constructed by the bridging effect of the bidentate carboxyl group of 3,5-bis(4-pyridylmethoxy)benzoate ligand. The catalytic activity of the Ca-complex was tested for the preparation of propargylamine in the A3 coupling reaction.
Reference Key
wang2017crystalssynthesis, Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Li-Hua Wang;Xin Wang;Xi-Shi Tai
Journal turk kardiyoloji dernegi arsivi
Year 2017
DOI
10.3390/cryst7030072
URL
http://www.mdpi.com/2073-4352/7/3/72
Keywords
synthesis 3

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