the short series of the oxygen-poor lanthanide oxide selenides m10ose14 with m = la–nd

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ID: 149952
2012
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Abstract
Single crystals and phase pure samples of oxygen-poor ternary lanthanide oxide selenides with the composition M10OSe14 (M = La–Nd; tetragonal, I41/acd; a = 1592.0–1559.8 pm, c = 2106.5–2062.9 pm) could be obtained by reacting the corresponding metals, selenium and selenium dioxide as oxygen source. Their crystal structures are isotypic with Pr10OS14 and thus contain isolated [OM4]10+ tetrahedra (d(O2––M3+) = 243–248 pm) embedded in a complex anionic {[M6Se14]10–} lanthanide selenide matrix (d(M3+–Se2–) = 288–358 pm). All three crystallographically independent M3+ cations exhibit eight contacts to chalcogenide anions (O2– and/or Se2–) resulting in the formation of bicapped trigonal prismatic coordination polyhedra. The optical band gaps of the oxide selenides M10OSe14 amount to values between 1.89 and 2.04 eV indicating wide band-gap semiconductors.
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Authors Frank A. Weber, Christian M. Schurz, Susanne Frunder, Charlotte F. Kuhn, Thomas Schleid
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Journal turk kardiyoloji dernegi arsivi
Year 2012
DOI
10.3390/cryst2031136
URL
http://www.mdpi.com/2073-4352/2/3/1136
Keywords
lanthanides oxide selenides

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