synthesis of novel derivatives of carbazole-thiophene, their electronic properties, and computational studies
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ID: 147664
2016
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Abstract
A series of carbazole-thiophene dimers, P1–P9, were synthesized using Suzuki-Miyaura and Ullmann coupling reactions. In P1–P9, carbazole-thiophenes were linked at the N-9 position for different core groups via biphenyl, dimethylbiphenyl, and phenyl. Electronic properties were evaluated by UV-Vis, cyclic voltammogram, and theoretical calculations. Particularly, the effects of conjugation connectivity on photophysical and electrochemical properties, as well as the correlation between carbazole-thiophene and the core, were studied. Carbazole connecting with thiophenes at the 3,6-positions and the phenyl group as a core group leads to increased stabilization of HOMO and LUMO energy levels where the bandgap (ΔE) is significantly reduced.
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damit2016journalsynthesis
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| Authors | ;E. F. Damit;N. Nordin;A. Ariffin;K. Sulaiman |
| Journal | british journal of psychology (london, england : 1953) |
| Year | 2016 |
| DOI |
10.1155/2016/9360230
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