Modulating vs. Templating: The Fine Tuning of Hierarchally Porous PCN-250 Using Fatty Acids for Engineering Guest Adsorption.

Clicks: 297
ID: 1467
2019
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Steady

Ranked #66 of 192 articles by views in angewandte chemie (international ed in english)

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 192 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Modulating and templating are two synthetic techniques that have garnered significant attention over the last several years for preparing Hierarchally Porous Metal-Organic Frameworks (HP-MOFs). Herein, by using fatty acids with different lengths and concentrations, which act as dual-functional modulators/templates, we are able to obtain HP-MOFs with tunable mesopores with different diameters and locations. We found that the length and concentration of the fatty acid determine if micelle foration can occur, which in turn dictates the porosity of the resulting HP-MOFs. The HP-MOFs with different mesopores exhibit distinct performances in gas uptake and dye adsorption and the structure-performance relationship is ascribed to the pore diameters and locations. This approach provides a potential universal method to efficiently introduce hierarchal mesopores into existing microporous MOF adsorbents with tunable properties.
Reference Key
kirchon2019modulating Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Kirchon, Angelo;Li, Jialuo;Xia, Fangqing;Day, Gregory S;Becker, Benjamin;Chen, Wenmiao;Sue, Hung-Jue;Fang, Yu;Zhou, Hong-Cai;
Journal angewandte chemie (international ed in english)
Year 2019
DOI
10.1002/anie.201905006
URL
Keywords Keywords not found

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.