Mechanosynthesis of Odd-Numbered Tetraaryl[n]cumulenes.
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2019
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Abstract
A mechanochemical synthesis of one-dimensional carbon allotrope carbyne model compounds, namely tetraaryl[n]cumulenes (n = 3, 5) was realized. Central for the mechanosynthesis of the cumulenic carbon nanostructures were the development of a mechanochemical Favorskii alkynylation-type reaction and the implementation of a solvent-free, acid-free reductive elimination with tin(II) chloride by ball milling.
| Reference Key |
ardila-fierro2019mechanosynthesis
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|---|---|
| Authors | Ardila-Fierro, Karen Janella;Bolm, Carsten;Hernández, José G; |
| Journal | angewandte chemie (international ed in english) |
| Year | 2019 |
| DOI |
10.1002/anie.201905670
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| URL | |
| Keywords | Keywords not found |
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