complete bromide surface segregation in mixed nacl/nabr aerosols grown from droplets

Clicks: 343
ID: 145841
2015
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Abstract
Sea-salt aerosols are a source of atmospheric bromine responsible for ozone depletion. The availability of bromine from sea-salt aerosols to heterogeneous phase chemical reactions is determined by its local concentration at the aerosol surface. We report here complete surface segregation of bromine in mixed NaCl/NaBr aerosols grown by drying droplets, thus mimicking the atmospheric process by which solid sea-salt aerosols are generated. For d=70  nm solid aerosols, complete surface segregation is observed for solution Br/Cl ratios below 2%. These findings set a size-dependent upper limit on the bromine surface enrichment that can be reached in solid salt aerosols grown from sea-water droplets in the atmosphere.
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antonsson2015physicalcomplete Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
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Journal american journal of transplantation
Year 2015
DOI
10.1103/PhysRevX.5.011025
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