phase behavior of undecane-dodecane mixtures confined in sba-15
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ID: 144802
2013
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Abstract
Phase behavior of undecane-dodecane mixtures (n-C11H24-C12H26, C11-C12) in bulk and confined in SBA-15 (pore diameters 3.8, 7.8, and 17.2 nm) has been studied by differential scanning calorimetry. Phase diagram of the confined C11-C12 system shows dependence on pore size, indicating simple behavior compared with the bulk. In the three systems, melting points of the confined C11, C12 and the mixtures (xC12 = 0.1–0.9) present a linear relation with the pore diameter from 3.8 to 17.2 nm. Melting behavior of the confined C11-C12 mixtures is closely as the confined C11, C12. Melting temperatures of the three systems have been fitted as a function of mole fraction xC12.
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yan2013journalphase
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| Authors | ;Xiao Yan;Hai-Rong Pei;Tong-Bo Wang;Wen-Bo Liu;Xiao-Zheng Lan |
| Journal | british journal of psychology (london, england : 1953) |
| Year | 2013 |
| DOI |
10.1155/2013/476236
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