kinetic study of selective gas-phase oxidation of isopropanol to acetone using monoclinic zro2 as a catalyst
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ID: 137267
2015
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Abstract
Zirconia was prepared by a precipitation method and calcined at 723 K, 1023 K, and 1253 K in order to obtain monoclinic zirconia. The prepared zirconia was characterized by XRD, SEM, EDX, surface area and pore size analyzer, and particle size analyzer. Monoclinic ZrO2 as a catalyst was used for the gas-phase oxidation of isopropanol to acetone in a Pyrex-glass-flow-type reactor with a temperature range of 443 K - 473 K. It was found that monoclinic ZrO2 shows remarkable catalytic activity (68%) and selectivity (100%) for the oxidation of isopropanol to acetone. This kinetic study reveals that the oxidation of isopropanol to acetone follows the L-H mechanism.
| Reference Key |
sadiq2015qumicakinetic
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|---|---|
| Authors | ;Mohammad Sadiq;Muhammad Ali;Razia Aman;Haroon Ur Rashid;Muhammad Naveed Umar |
| Journal | greece and rome |
| Year | 2015 |
| DOI |
10.5935/0100-4042.20150097
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| URL | |
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