the influence of substituted aromatic aldehydes on zn-mn alloy electrodeposition

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ID: 137161
2013
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Abstract
Additives are necessary in the electrodeposition of Zn-Mn alloys at high current density, in order to reduce hydrogen evolution reaction and prevent dendrite formation. The influence of two aromatic aldehydes, 4-hydroxy-benzaldehyde and 3,4-dimethoxy-benzaldehyde, as the additives in Zn-Mn plating electrolyte, is examined in this work. The coatings characterization by scanning electron microscopy and X-ray energy dispersive spectroscopy, as well as the examination of additives effect by electrochemical methods, indicate a complex involvement of additive molecules in hydrogen evolution, as well as in Zn2+ and Mn2+ reduction. Consequently, the levelling action can be achieved and the chemical composition of the Zn-Mn alloy can be tailored, by adding the proper additive type and concentration in the plating electrolyte. [Projekat Ministarstva nauke Republike SRbije, br. III 45019]
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Authors ;Bučko Mihael;Lačnjevac Uroš;Bajat Jelena
Journal meditsinskaia radiologiia
Year 2013
DOI
10.2298/JSC130118025B
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