generation of supramolecular chirality around twofold rotational or helical axes in crystalline assemblies of achiral components

Clicks: 237
ID: 136924
2015
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Abstract
A multi-point approximation method clarifies supramolecular chirality of twofold rotational or helical assemblies as well as bundles of the one-dimensional (1D) assemblies. While one-point approximation of materials claims no chirality generation of such assemblies, multi-point approximations do claim possible generation in the 1D assemblies of bars and plates. Such chirality derives from deformations toward three-axial directions around the helical axes. The chiral columns are bundled in chiral ways through symmetry operations. The preferable right- or left-handed columns are bundled together to yield chiral crystals with right- or left-handedness, respectively, indicating that twofold helix symmetry operations cause chiral crystals composed of achiral components via a three-stepwise and three-directional process.
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miyata2015symmetrygeneration Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Mikiji Miyata;Norimitsu Tohnai;Ichiro Hisaki;Toshiyuki Sasaki
Journal journal of hospitality and tourism management
Year 2015
DOI
10.3390/sym7041914
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