stability of epidoxorubicin hydrochloride in aqueous solutions: experimental and theoretical studies

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ID: 136793
2017
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Abstract
The first-order degradation kinetics of epidoxorubicin were investigated as a function of pH, temperature, and buffers concentrations. The degradation was followed by HPLC. Buffer catalysis was observed in acetate and phosphate buffers. The pH-rate profiles were obtained at 333, 343, 353, and 363 K. The pH-rate expression was kpH=k1×aH+×f1+k2×f1+k3×f2+(k4×f2+k5×f3)×aOH-, where k1, k4, and k5 are the second-order rate constants (mol−1 L s−1) for hydrogen ion activity and for hydroxyl ion activity, respectively, and k2 and k3 are the first-order constants (s−1) for spontaneous reaction under the influence of water. Epidoxorubicin demonstrates the greatest stability in the pH range 3–5. The electrostatic molecular potential orbitals HOMO-LUMO were also defined in order to determine the cause of the reactivity of particular epidoxorubicin molecule domains in solutions with various pH values.
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sobczak2017journalstability Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Agnieszka Sobczak;Monika A. Lesniewska-Kowiel;Izabela Muszalska;Artur Firlej;Judyta Cielecka-Piontek;Szymon Tomczak;Bolesław Barszcz;Irena Oszczapowicz;Anna Jelińska
Journal british journal of psychology (london, england : 1953)
Year 2017
DOI
10.1155/2017/8107140
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