Isolation and structural characterization of eight-fold protonated octacyanometallates [M(CNH)8]4+ (M=MoIV,WIV) from Superacids.
Clicks: 293
ID: 101144
2020
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This
article has not been analysed, so there is no overall score —
reader engagement is measured and shown alongside.
Reader Engagement
Emerging Content
30.0
/100
293 views
43 readers
AI Quality Assessment
Not analyzed
Readership in this journal
EmergingRanked #71 of 192 articles by views in angewandte chemie (international ed in english)
Most read
Least read
Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 192 in total.
Mint this article as an NFT
Not yet mintedCreate a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.
5
SUSD
one-off · no wallet required
Abstract
Octacyanometallates K 4 [Mo(CN) 8 ] and K 4 [W(CN) 8 ] are completely protonated in superacidic mixtures of anhydrous hydrogen fluoride and antimony pentafluoride. The resulting hydrogen isocyanide complexes [Mo(CNH) 8 ] 4+ [SbF 6 ] - 4 and [W(CNH) 8 ] 4+ [SbF 6 ] - 4 are the first examples of eight-coordinate homoleptic metal complexes containing hydrogen isocyanide (CNH) ligands. The complexes were crystallographically characterized, revealing hydrogen-bonded networks with short N … H … F contacts. Low-temperature NMR measurements in HF confirmed rapid proton exchange even at -40 °C. Upon protonation, ṽ(C≡N) increases of about 50 cm -1 which is in agreement with DFT-calculations.
| Reference Key |
sellin2020isolationangewandte
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | Sellin, Malte;Marvaud, Valérie;Malischewski, Moritz; |
| Journal | angewandte chemie (international ed in english) |
| Year | 2020 |
| DOI |
10.1002/anie.202002366
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.