Transition-Metal-Free Coupling Reaction of Dithiocarbamates with Indoles: C-S Bond Formation.

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ID: 95438
2018
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Abstract
A one-pot three-component route for the direct introduction of dithiocarbamates into indoles using a C-H sulfenylation strategy mediated by molecular iodine is disclosed. Various indole derivatives including 1-methylindole, 2-methylindole, 3-methylindole, and 5-substituted indoles were applied successfully in this protocol to afford diverse indole-dithiocarbamates containing the dithiocarbamate group on the position two or three in good to high yields. The reactions do not require transition metals or disulfiram but use an environmentally benign solvent and simple commercially available starting materials.
Reference Key
halimehjani2018transitionmetalfreethe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Halimehjani, Azim Ziyaei;Shokrgozar, Sahar;Beier, Petr;
Journal The Journal of organic chemistry
Year 2018
DOI
10.1021/acs.joc.8b00206
URL
Keywords
Cancer copper dithiocarbamate prochelators γ-glutamyl transpeptidase

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