Beyond Ternary OPV: High-Throughput Experimentation and Self-Driving Laboratories Optimize Multicomponent Systems.

Clicks: 343
ID: 95111
2020
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Abstract
Fundamental advances to increase the efficiency as well as stability of organic photovoltaics (OPVs) are achieved by designing ternary blends, which represents a clear trend toward multicomponent active layer blends. The development of high-throughput and autonomous experimentation methods is reported for the effective optimization of multicomponent polymer blends for OPVs. A method for automated film formation enabling the fabrication of up to 6048 films per day is introduced. Equipping this automated experimentation platform with a Bayesian optimization, a self-driving laboratory is constructed that autonomously evaluates measurements to design and execute the next experiments. To demonstrate the potential of these methods, a 4D parameter space of quaternary OPV blends is mapped and optimized for photostability. While with conventional approaches, roughly 100 mg of material would be necessary, the robot-based platform can screen 2000 combinations with less than 10 mg, and machine-learning-enabled autonomous experimentation identifies stable compositions with less than 1 mg.
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langner2020beyondadvanced Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Langner, Stefan;Häse, Florian;Perea, José Darío;Stubhan, Tobias;Hauch, Jens;Roch, Loïc M;Heumueller, Thomas;Aspuru-Guzik, Alán;Brabec, Christoph J;
Journal advanced materials (deerfield beach, fla)
Year 2020
DOI
10.1002/adma.201907801
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