High-Throughput Synthesis of Chiroptical Nanostructures from Synergistic Hydrogen-Bonded Coassemblies.

Klik: 280
ID: 93782
2020
Metrik Kualitas & Kinerja Artikel
Kualitas Keseluruhan
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
Penilaian Kualitas AI
Belum dianalisis
Readership in this journal
Emerging

Ranked #59 of 150 articles by views in acs nano

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 150 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstrak
The emergence, amplification, and manipulation of chiroptical activity in self-assembled nanostructures, including circularly polarized absorbance and luminescence (CPL), remain considerable challenges. Here, we report the high-throughput synthesis of nanostructures with finely tailored chiroptical activities. Two fully π-conjugated benzimidazoles formed H-bonded complexes with natural hydroxyl acids (tartaric acid and mandelic acid), which self-assembled into diversified macroscopically chiral nanostructures. Synergistic coassembly allows for the emergence of Cotton effects and CPL with high dissymmetry -factors ( up to 8 × 10, up to 3 × 10). The tartaric acid coassembled system exhibits enantiomer-independent left-handed CPL, which transforms into a cooperative ternary coassembly appended with enantiomer-resolved CPL with extended emission wavelength upon selective transition metal ion chelation. This H-boned coassembly system provides a vast number of chiral nanostructures with flexibly tuned Cotton effects and CPL, which also behaves as a selective chiroptical sensor to metal ions.
Kunci Referensi
zhao2020highthroughputacs Gunakan kunci ini untuk mengutip otomatis dalam naskah saat menggunakan SciMatic Manuscript Manager atau Thesis Manager
Penulis Zhao, Jianjian;Liu, Yaqing;Hao, Aiyou;Xing, Pengyao;
Jurnal acs nano
Tahun 2020
DOI
10.1021/acsnano.0c00352
URL
Kata Kunci
hydrogen bonding self-assembly chiral nanostructures circularly polarized light supramolecular chirality

Sitasi

Tidak ada sitasi yang ditemukan. Untuk menambahkan sitasi, hubungi admin di info@scimatic.org

Komentar

Belum ada komentar. Jadilah yang pertama berkomentar pada artikel ini.