Integrating pyrolysis and ex-situ catalytic reforming by microwave heating to produce hydrocarbon-rich bio-oil from soybean soapstock.

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ID: 90261
2020
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Abstract
The composite catalysts were synthesized with SiC powder and ZSM-5 and were characterized by Brunauer-Emmett-Teller, X-ray diffraction, thermogravimetric analysis, pyridine-infrared spectroscopy, and scanning electron microscopy. The catalysts showed a high heating rate and excellent catalytic performance for pyrolysis vapors, and the product fractional distribution and chemical compositions of bio-oil in a tandem system (microwave pyrolysis and microwave ex-situ catalytic reforming) was examined. Experimental results confirmed the quality of bio-oil produced by the microwave-induced catalytic reforming was better than that product through electric heating. Additionally, 36.94 wt% of bio-oil was obtained using the catalyst with 20%ZSM-5/SiC under the following conditions: feed-to-catalyst ratio, 2:1; pyrolysis temperature, 550 °C; and catalytic temperature, 350 °C. The selectivities of hydrocarbons reached up to 75.88%. After five cycles, the activity of the regenerated composite catalyst was retained at 95% of the original catalyst.
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jiang2020integratingbioresource Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Jiang, Lin;Wang, Yunpu;Dai, Leilei;Yu, Zhenting;Wu, Qiuhao;Zhao, Yunfeng;Liu, Yuhuan;Ruan, Roger;Ke, Linyao;Peng, Yujie;Xia, Donghua;Jiang, Li;
Journal Bioresource technology
Year 2020
DOI
S0960-8524(20)30112-7
URL
Keywords
Microwave catalytic pyrolysis composite catalyst soybean soapstock zsm-5

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