Exploratory analysis and ranking of analytical procedures for short-chain chlorinated paraffins determination in environmental solid samples.

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ID: 85784
2019
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Abstract
Short-chain chlorinated paraffins are ones of the most recent chemical compounds that have been classified as persistent organic pollutants. They have various applications and are emitted to the environment. Despite the fact, that the content levels of these compounds in the environmental compartments should be monitored, there is still a lack of well-defined and validated analytical procedures, proposed or suggested by the national or international environmental protection agencies. Finding an appropriate analytical procedure (sensitive and green at the same time) from many available ones is very often a difficult task. Therefore it can be supported with multicriteria decision analysis. The dataset consisting of 22 procedures was described by 7 criteria, mainly referring to procedures greenness. The data treatment with cluster analysis and principal component analysis revealed the internal structure of the dataset. Moreover, both statistical tools allowed for reduction of dataset criteria to three. This was used for applying ternary plot to show the multicriteria decision analysis results within all possible weights. With the aid of chemometric and multicriteria decision analysis tools it was easy to assess the set of analytical procedure. Depending on the applied weights to assessment criteria different analytical procedures are the most appropriate (winners).
Reference Key
mar2019exploratorythe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Marć, Mariusz;Bystrzanowska, Marta;Tobiszewski, Marek;
Journal The Science of the total environment
Year 2019
DOI
S0048-9697(19)34656-X
URL
Keywords
principal component analysis cluster analysis multicriteria decision analysis short-chain chlorinated paraffins solid samples technique for order of preference by similarity to ideal solution

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