Synthesis, characterization, and energetic properties of 6-amino-tetrazolo[1,5-b]-1,2,4,5-tetrazine-7-N-oxide: a nitrogen-rich material with high density.

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ID: 83181
2015
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Abstract
The synthesis and energetic properties of a novel N-oxide high-nitrogen compound, 6-amino-tetrazolo[1,5-b]-1,2,4,5-tetrazine-7-N-oxide, are described. Resulting from the N-oxide and fused rings system, this molecule exhibits high density, excellent detonation properties, and acceptable impact and friction sensitivities, which suggests potential applications as an energetic material. Compared to known high-nitrogen compounds, such as 3,6-diazido-1,2,4,5-tetrazine (DiAT), 2,4,6-tri(azido)-1,3,5-triazine (TAT), and 4,4',6,6'-tetra(azido)azo-1,3,5-triazine (TAAT), a marked performance and stability increase is seen. This supports the superior qualities of this new compound and the advantage of design strategy.
Reference Key
wei2015synthesischemistry Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Wei, Hao;Zhang, Jiaheng;Shreeve, Jean'ne M;
Journal Chemistry, an Asian journal
Year 2015
DOI
10.1002/asia.201500086
URL
Keywords
n-oxide tetrazole nitrogen-rich compounds tetrazine ∧energetic materials

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