Effect of Environmental Temperature on the Content of Impurity Li3V2(PO4)3/C in LiVPO4F/C Cathode for Lithium-ion Batteries
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ID: 82771
2018
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Abstract
Previous studies have shown that the impurity Li3V2(PO4)3 in LiVPO4F will adversely affect its electrochemical performance. In this work, we show that the crystalline composition of LiVPO4F/C is mainly influenced by the environmental temperature. The content of Li3V2(PO4)3 formed in LiVPO4F/C is 0, 11.84 and 18.75% at environmental temperatures of 10, 20, and 30°C, respectively. For the sample LVPF-30C, the SEM pattern shows a kind of alveolate microstructure and the result of selected area electron diffraction shows two sets of patterns. The LiVPO4F/C cathode without impurity phase Li3V2(PO4)3 was prepared at 10°C. The selected area electron diffraction result proves that the lattice pattern of LiVPO4F is a regular parallelogram. Electrochemical tests show that only one flat plateau around 4.2 V appears in the charge/discharge curve, and the reversible capacity is 140.4 mAh·g−1 at 0.1 C, and 116.3 mAh·g−1 at 5 C. From these analyses, it is reasonable to speculate that synthesizing LiVPO4F/C at a low environmental temperature is a practical strategy to obtain pure crystalline phase and good electrochemical performance.
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zeng2018effectfrontiers
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| Authors | Zeng, Taotao;Fan, Changling;Fan, Changling;Wen, Zheng;Li, Qiyuan;Zhou, Zeyan;Han, Shaochang;Liu, Jinshui;Liu, Jinshui; |
| Journal | Frontiers in chemistry |
| Year | 2018 |
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