Synchrotron-Radiation X-Ray Investigation of Li+/Na+ Intercalation into Prussian Blue Analogues

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ID: 82769
2013
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Abstract
Prussian blue analogies (PBAs) are promising cathode materials for lithium ion (LIB) and sodium ion (SIB) secondary batteries, reflecting their covalent and nanoporous host structure. With use of synchrotron-radiation (SR) X-ray source, we investigated the structural and electronic responses of the host framework of PBAs against Li+ and Na+ intercalation by means of the X-ray powder diffraction (XRD) and X-ray absorption spectroscopy (XAS). The structural investigation reveals a robust nature of the host framework against Li+ and Na+ intercalation, which is advantageous for the stability and lifetime of the batteries. The spectroscopic investigation identifies the redox processes in respective plateaus in the discharge curves. We further compare these characteristics with those of the conventional cathode materials, such as, LiCoO2, LiFePO4, and LiMn2O4.
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moritomo2013synchrotronradiationadvances Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Moritomo, Yutaka;Takachi, Masamitsu;Kurihara, Yutaro;Matsuda, Tomoyuki;
Journal advances in materials science and engineering
Year 2013
DOI
DOI not found
URL
http://dx.doi.org/10.1155/2013/967285
Keywords
Materials of engineering and construction. Mechanics of materials Engineering (General). Civil engineering (General)

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