Decorating g-CN with alkalinized TiC MXene for promoted photocatalytic CO reduction performance.
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2019
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Abstract
Photocatalytic reduction of carbon dioxide (CO) under visible light irradiation for producing high-value fuel has attracted tremendous attention in recent years. In this study, titanium carbide MXene (TiC) was used as a noble metal-free co-catalyst by simply mixing graphitic carbon nitride (g-CN) and alkalized TiC. The carbon monoxide evolution rate of the optimized composite (5%TCOH-CN) from photocatalytic reduction of CO was 5.9 times higher than that of pure g-CN. Alkalized TiC was responsible for the superior photocatalytic activity due to its excellent electrical conductivity and large CO adsorption capacity. Furthermore, the separation of the photo-induced electron-hole pairs was greatly enhanced because of the large Fermi level difference between alkalized TiC and pure g-CN. This work demonstrates the potential of MXenes as noble metal-free co-catalyst for photocatalysis processes such as carbon dioxide reduction reaction and nitrogen reduction reaction.
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tang2019decoratingjournal
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| Authors | Tang, Qijun;Sun, Zhuxing;Deng, Shuang;Wang, Haiqiang;Wu, Zhongbiao; |
| Journal | Journal of colloid and interface science |
| Year | 2019 |
| DOI |
S0021-9797(19)31558-9
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