Photo-Induced Heterogeneous C-H Arylation by Reusable Hybrid-Copper Catalyst.

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2020
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Abstract
Heterogeneous copper-catalysis enabled photo-induced C-H arylations under exceedingly mild conditions at room temperature. The versatile hybrid-copper catalyst provided step-economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid-copper catalyst could be reused without significant loss of catalytic efficacy. Detailed studies in terms of TEM, HRTEM and XPS analysis of the hybrid-copper catalyst, among others, supported its outstanding stability and reusability.
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Authors Choi, Isaac;Müller, Valentin;Lole, Gaurav;Köhler, Robert;Karius, Volker;Viöl, Wolfgang;Jooß, Christian;Ackermann, Lutz;
Journal Chemistry (Weinheim an der Bergstrasse, Germany)
Year 2020
DOI
10.1002/chem.202000192
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