Peanut Leaf Inspired Hybrid MOF with Humidity Responsive Wettability: towards Controllable Separation of Diverse Emulsions.

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ID: 80730
2020
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Abstract
Damage to the responsive superwetting material by external stimuli during the responsive process has been a ticklish question in recent years. We overcome this barrier by imitating peanut leaf and design a humidity responsive MIL-100 (Fe)/octadecylamine coated stainless steel mesh (HR-MOS). Such a material shows superhydrophilicity when ambient humidity is higher than saturated humidity, while shows superhydrophobicity and high adhesion to water when ambient humidity is lower than saturated humidity. The peanut leaf-liked two-level nanostructure of MIL-100 (Fe) is speculated as the principal factor to bring about the binary synergy wettability of the material. Accordingly, the material can realize humidity controlled separation of at least 12 types of emulsions along with satisfactory durability. The responsive condition of the material is mild and green, which has lower damage to the material and environment. The strategy is the first to realize humidity responsive wettability transition, and provides a novel approach for manually controlled environmental protection.
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Authors Qu, Ruixiang;Zhang, Weifeng;Li, Xiangyu;Liu, Yanan;Wei, Yen;Feng, Lin;Jiang, Lei;
Journal ACS applied materials & interfaces
Year 2020
DOI
10.1021/acsami.9b21118
URL
Keywords
membrane transport molecular biophysics protein translocation structural biology abc transporter clostridium thermocellum cryoem

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