Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0).

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ID: 80650
2020
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Abstract
An --biphenyl moiety-incorporated 32π hexaphyrin(3.1.1.3.1.1) is successfully achieved. Replacing with connectivity in the biphenyl unit of hexaphyrin leads to the formation of its structural isomer, octaphyrin(1.1.1.0.1.1.1.0). Spectral and structural analyses reveal the lack of planarity in hexaphyrin and the presence of an -arene unit in octaphyrin, thus affording nonaromatic characteristics.
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chitranshi2020structurallyorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Chitranshi, Sangya;Das, Mainak;Adinarayana, B;Cha, Won-Young;Kim, Dongho;Srinivasan, A;
Journal Organic letters
Year 2020
DOI
10.1021/acs.orglett.9b04614
URL
Keywords
melanoma metastasis gpx4 prc2 cdr1as ezh2 igf2bp linc00632 circrna mir-7

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