Magnetic Organic-Inorganic Nanohybrid for Efficient Modification of Paraffin Hydrocarbon Crystallization in Model Oil.

Crystallization modification has been applied in many fields, such as materials science, petroleum engineering, and chemical engineering. The modification of organic-inorganic hybrids via paraffin hydrocarbon crystallization has been significantly important for the exploration of undersea oil and gas resources. In this work, a metal oxide organic-inorganic hybrid pour point depressant (MOIH-PPD) is provided along with an analysis of the microscopic structure of the paraffin hydrocarbon crystal employing small-angle X-ray scattering and X-ray diffraction. The MOIH-PPD modified crystal grain exhibited a decrease in the long period and in the radius of gyration of the crystal grain and an increase in the thickness of the interface layer compared with those of the unmodified paraffin crystal. In addition, the synergistic effect of heterogeneous nucleation and the magnetic response of MOIH-PPD on the paraffin hydrocarbon system was also investigated, revealing that the synergism modification yields stress superior to that of MOIH-PPD or magnetic field alone, which provides insight into the possibility of the modification of paraffin hydrocarbon crystallization.