Halogen-Bond-Mediated Self-Assembly of Polymer-Resorcinarene Complexes.

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ID: 76714
2019
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Abstract
A new supramolecular system based on halogen-bonded macromolecular substances is presented. Binding and complex formation between a halogen bond acceptor N-benzyl ammonium resorcinarene bromide and a library of polymeric halogen bond donors based on iodotetrafluorophenoxy functionality is shown. The complex formation was confirmed in liquid state by dynamic light scattering and transmission electron microscopy. Spectroscopic measurements in the solid state verify the halogen bonding. In particular, the study shows that both homopolymers and polyethylene glycol block copolymers act as effective halogen bond donors leading to polymer-architecture-dependent complex morphologies.
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vlimki2019halogenbondmediatedmacromolecular Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Välimäki, Salla;Gustavsson, Lotta;Beyeh, Ngong Kodiah;Linko, Veikko;Kostiainen, Mauri A;
Journal Macromolecular rapid communications
Year 2019
DOI
10.1002/marc.201900158
URL
Keywords
Raman Spectroscopy supramolecular self-assembly halogen bonding resorcinarene reversible addition fragmentation chain transfer polymerization

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