Halogen bonding and host-guest chemistry between -alkylammonium resorcinarene halides, diiodoperfluorobutane and neutral guests.

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ID: 76711
2019
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Abstract
Single crystal X-ray structures of halogen-bonded assemblies formed between host -hexylammonium resorcinarene bromide () or -cyclohexylammonium resorcinarene chloride (), and 1,4-diiodooctafluorobutane and accompanying small solvent guests (methanol, acetonitrile and water) are presented. The guests' inclusion affects the geometry of the cavity of the receptors and , while the divalent halogen bond donor 1,4-diiodooctafluorobutane determines the overall nature of the halogen bond assembly. The crystal lattice of contains two structurally different dimeric assemblies A and B, formally resulting in the mixture of a capsular dimer and a dimeric pseudo-capsule. H and F NMR analyses supports the existence of these halogen-bonded complexes and enhanced guest inclusion in solution.
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Authors Pan, Fangfang;Dashti, Mohadeseh;Reynolds, Michael R;Rissanen, Kari;Trant, John F;Beyeh, Ngong Kodiah;
Journal Beilstein journal of organic chemistry
Year 2019
DOI
10.3762/bjoc.15.91
URL
https://doi.org/10.3762/bjoc.15.91
Keywords
X-ray crystallography halogen bonding capsule dimeric assemblies host–guest chemistry resorcinarene salts

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