Halogen bonding and host-guest chemistry between -alkylammonium resorcinarene halides, diiodoperfluorobutane and neutral guests.

Clicks: 436
ID: 76711
2019
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #15 of 50 articles by views in Beilstein journal of organic chemistry

Most read Least read

Bar heights use a square-root scale.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Single crystal X-ray structures of halogen-bonded assemblies formed between host -hexylammonium resorcinarene bromide () or -cyclohexylammonium resorcinarene chloride (), and 1,4-diiodooctafluorobutane and accompanying small solvent guests (methanol, acetonitrile and water) are presented. The guests' inclusion affects the geometry of the cavity of the receptors and , while the divalent halogen bond donor 1,4-diiodooctafluorobutane determines the overall nature of the halogen bond assembly. The crystal lattice of contains two structurally different dimeric assemblies A and B, formally resulting in the mixture of a capsular dimer and a dimeric pseudo-capsule. H and F NMR analyses supports the existence of these halogen-bonded complexes and enhanced guest inclusion in solution.
Reference Key
pan2019halogenbeilstein Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Fangfang Pan, Mohadeseh Dashti, Michael R Reynolds, Kari Rissanen, John F Trant, Ngong Kodiah Beyeh
Are you one of these authors? Claim your profile
Journal Beilstein journal of organic chemistry
Year 2019
DOI
10.3762/bjoc.15.91
URL
https://doi.org/10.3762/bjoc.15.91
Keywords
X-ray crystallography halogen bonding capsule dimeric assemblies host–guest chemistry resorcinarene salts

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.