A Calix[4]resorcinarene-Based [Co] Coordination Cage for Highly Efficient Cycloaddition of CO to Epoxides.
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2019
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Abstract
The design and synthesis of polynuclear metal cluster-based coordination cages is of considerable interest due to their appealing structural characteristics and potential applications. Herein, we report a calix[4]resorcinarene-based [Co] coordination cage, [Co(TPC4R-I)(1,3-BDC)(μ-OH)(HO)(DMF)]·7DMF·23HO (), assembled with 2 bowl-shaped calix[4]resorcinarenes (TPC4R-I), 10 angular 1,3-benzenedicarboxylates (1,3-BDC), and 12 Co(II) cations. Remarkably, it is shown to be a highly efficient recyclable heterogeneous catalyst for CO conversion due to its exposed Co(II) Lewis acid sites.
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guo2019ainorganic
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| Authors | Guo, Ting-Ting;Su, Xiao-Fang;Xu, Xianxiu;Yang, Jin;Yan, Li-Kai;Ma, Jian-Fang; |
| Journal | Inorganic chemistry |
| Year | 2019 |
| DOI |
10.1021/acs.inorgchem.9b02473
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