A novel molecularly imprinted electrochemical sensor based on double sensitization by MOF/CNTs and Prussian blue for detection of 17β-estradiol.
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2019
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Abstract
In this paper, we constructed MIL-53 (AlOHbdc, bdc = benzene-1,4-dicarboxylate) /CNTs and Prussian blue (PB) as the double sensitization material of the sensing platform, in which the MIL-53/CNTs hybrid can not only increase the specific surface area but also increase the conductivity of the sensor and PB can play a role in amplifying electrical signals and accelerating electron transmission. Pyrrole was used as monomer and E2 was used as template for electropolymerization to form conductive film. Moreover, the overoxidation/dedoping elution method were used to simplify the experimental process. Under optimal conditions, the MIECS exhibited an excellent sensitivity and high selectivity with a wide linear response range between 10 to 10 mol L and an estimated detection limit of 6.19 × 10 mol L.
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duan2019abioelectrochemistry
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| Authors | Duan, Dingding;Si, Xiaojing;Ding, Yaping;Li, Li;Ma, Guohong;Zhang, Lu;Jian, Bingyu; |
| Journal | Bioelectrochemistry (Amsterdam, Netherlands) |
| Year | 2019 |
| DOI |
S1567-5394(18)30567-X
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