A novel molecularly imprinted electrochemical sensor based on double sensitization by MOF/CNTs and Prussian blue for detection of 17β-estradiol.

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ID: 76634
2019
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Ranked #4 of 14 articles by views in Bioelectrochemistry (Amsterdam, Netherlands)

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Abstract
In this paper, we constructed MIL-53 (AlOHbdc, bdc = benzene-1,4-dicarboxylate) /CNTs and Prussian blue (PB) as the double sensitization material of the sensing platform, in which the MIL-53/CNTs hybrid can not only increase the specific surface area but also increase the conductivity of the sensor and PB can play a role in amplifying electrical signals and accelerating electron transmission. Pyrrole was used as monomer and E2 was used as template for electropolymerization to form conductive film. Moreover, the overoxidation/dedoping elution method were used to simplify the experimental process. Under optimal conditions, the MIECS exhibited an excellent sensitivity and high selectivity with a wide linear response range between 10 to 10 mol L and an estimated detection limit of 6.19 × 10 mol L.
Reference Key
duan2019abioelectrochemistry Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Duan, Dingding;Si, Xiaojing;Ding, Yaping;Li, Li;Ma, Guohong;Zhang, Lu;Jian, Bingyu;
Journal Bioelectrochemistry (Amsterdam, Netherlands)
Year 2019
DOI
S1567-5394(18)30567-X
URL
Keywords
prussian blue metal-organic frameworks 17β-estradiol polypyrrole molecularly imprinted electrochemical sensor

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