Direct Formation and Structural Characterization of Electride C12A7.

Clicks: 362
ID: 762
2018
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Steady

Ranked #78 of 812 articles by views in Materials (Basel, Switzerland)

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 812 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
CaAlO (C12A7 or Mayenite) is a material whose caged clathrate structure and occluded anionic species leads to significant functionality. The creation of occluded anionic vacancies leads to the injection of localized electrons at the center of the cage, converting the wide band gap insulator to a semi- or metallic conducting material. The conversion to the electride historically requires the synthesis of oxy-C12A7, consolidation, and then reduction to introduce anionic vacancies. This report develops and characterizes an electride formation procedure from three starting points: unconsolidated oxy-C12A7, heterogenous solid-state reactants (CaCO₃ and Al₂O₃), and homogenous non-carbonaceous polymer assisted sol-gel reactants. Electride-C12A7 formation is observed in a vacuum furnace where the reactants are in direct contact with a carbon source. Process time and temperature-dependent structural characterization provides insight into the source of high temperature C12A7 stability, the mechanism of anionic vacancy formation, and the magnitude of ultimate conductivity that cannot be explained by current reduction theories. A new theory is presented where mixed O- and C-occupied cages lead to high temperature stability, oxidation of C species creates anionic vacancies, and an equilibrium between the reducing power of the electride-C12A7 and of the C species leads to the ultimate conductivity achieved by the process. This represents a shift in understanding of the carbonaceous reduction process and the first report of high purity electride-C12A7 formation from heterogenous solid-state reactants and homogenous non-carbonaceous polymer assisted sol-gel reactants.
Reference Key
salasin2018direct Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Salasin, J R;Schwerzler, S E A;Mukherjee, R;Keffer, D J;Sickafus, K E;Rawn, C J;
Journal Materials (Basel, Switzerland)
Year 2018
DOI
E84
URL
Keywords
ecological risk assessment heavy metal contamination karst plateau lakeshore wetland land uses conversion Fog computing internet of things (iot) iot architecture smart cities smart agriculture lorawan fiware iot platform low power wide area network (lpwan) Deep learning dementia Convolutional neural network classification alzheimer’s disease batch normalization

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.