Self-powered Cascade Bipolar Electrodes with Fluorimetric Readout.

Clicks: 391
ID: 65875
2019
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #14 of 194 articles by views in Analytical chemistry

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 194 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Bipolar electrodes working in a self-powered mode are a basis for development of easy to use electrochemical-optical sensors, these systems are very promising due to their simplicity and no need of external polarization. However, the self-powered mode can be used only in cases when the redox potential difference of reactions occurring at opposite poles of the electrode is sufficiently high. To overcome this limitation we propose development of a system working spontaneously, but involving two bipolar electrodes, forming a cascade system. One of electrodes ('driving' electrode) works in self-powered mode and triggers charge transfer processes in the second ('sensing') bipolar electrode. For the sensing electrode an electrochemical process of an analyte occurs at one pole, accompanied by a complementary process at the second pole, inducing an optical (fluorimetric) analytical signal. This concept was successfully tested on a model system of a sensing bipolar electrode with a platinum electrode participating in oxidation of an analyte, L-ascorbic acid, connected with electrode coated by poly(3-octylthiophene), where reduction of the polymer results in formation of fluorimetrically active neutral form. As the driving system bipolar electrodes with zinc wire as one pole, characterized by a low redox potential, were used.
Reference Key
jaworska2019selfpoweredanalytical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Jaworska, Ewa;Michalska, Agata;Maksymiuk, Krzysztof;
Journal Analytical chemistry
Year 2019
DOI
10.1021/acs.analchem.9b03405
URL
Keywords
self-concept body dissatisfaction confirmation body change behaviors college men

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.