Copper-catalyzed acylation of pyrazolones with aldehydes to afford 4-acylpyrazolones.
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2019
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Abstract
Copper-catalyzed direct acylation of the alkenyl C-H bond in 1,2-dihydro-3H-pyrazol-3-ones has been developed, affording a series of 4-acylpyrazolones in moderate to good yields. Notably, this protocol involves readily accessible substrates and reagents, which have good functional group tolerance leading to pyrazolone derivatives under mild reaction conditions.
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xiao2019coppercatalyzedorganic
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| Authors | Xiao, Yan;Wu, Xiaopeng;Teng, Jiangang;Sun, Song;Yu, Jin-Tao;Cheng, Jiang; |
| Journal | Organic & biomolecular chemistry |
| Year | 2019 |
| DOI |
10.1039/c9ob01486a
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