1,6-Conjugate-Addition-Induced [2 + 1] Annulation of -Quinone Methides and Pyrazolones: Synthesis of Bis-Spiro Compounds with Contiguous Quaternary Spiro-Centers.

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ID: 64660
2019
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Abstract
A diastereoselective formal 1,6-conjugate-addition-mediated [2 + 1] annulation reaction using -quinone methides and pyrazolones has been described. The corresponding bis-spiro[cyclohexadienone-cyclopropane-pyrazolone] compounds were obtained in very good yield under mild reaction conditions.
Reference Key
kale201916conjugateadditioninducedorganic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Kale, Someshwar B;Jori, Popat K;Thatikonda, Thanusha;Gonnade, Rajesh G;Das, Utpal;
Journal Organic letters
Year 2019
DOI
10.1021/acs.orglett.9b02641
URL
Keywords
uplc-ms/ms monosaccharide composition polyporus umbellatus polysaccharide pre-column derivation

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