An intramolecular inverse electron demand Diels–Alder approach to annulated α-carbolines
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2012
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Abstract
Intramolecular inverse electron demand cycloadditions of isatin-derived 1,2,4-triazines with acetylenic dienophiles tethered by amidations or transesterifications proceed in excellent yields to produce lactam- or lactone-fused α-carbolines. Beginning with various isatins and alkynyl dienophiles, a pilot-scale library of eighty-eight α-carbolines was prepared by using this robust methodology for biological evaluation.
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ma2012anbeilstein
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| Authors | Ma, Zhiyuan;Ni, Feng;Woo, Grace H. C.;Lo, Sie-Mun;Roveto, Philip M.;Schaus, Scott E.;Snyder, John K.; |
| Journal | Beilstein journal of organic chemistry |
| Year | 2012 |
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