Visible-light-mediated deuteration of silanes with deuterium oxide.

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ID: 58193
2019
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Abstract
Isotopically labeled compounds are highly desirable as they can serve as both mechanistic probes in chemistry and diagnostic tools in medicinal research. Herein, we report an unprecedented visible-light-mediated metal-free deuteration of silanes using DO as an inexpensive, readily available, and easy to handle deuterium source. A broad range of aryl- and alkyl-substituted silanes were deuterated with high deuterium incorporations and yields. Furthermore, a 100 gram-scale synthesis was demonstrated using continuous-flow micro-tubing reactors, where enhanced reaction efficiency was obtained. The photoredox-catalyzed polarity matched hydrogen atom transfer (HAT) between silanes and the thiol HAT catalyst was responsible for the efficient deuteration.
Reference Key
zhou2019visiblelightmediatedchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Zhou, Rong;Li, Jiesheng;Cheo, Han Wen;Chua, Rachel;Zhan, Gu;Hou, Zhaomin;Wu, Jie;
Journal Chemical science
Year 2019
DOI
10.1039/c9sc02818h
URL
Keywords
sodium-ion batteries energy storage bismuth anodes nanoparticle@carbon composites

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