Site-Selective Carbonylative Synthesis of Structurally Diverse Lactams from Heterocyclic Amines with TFBen as the CO Source.

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ID: 58187
2019
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Abstract
A palladium-catalyzed site-selective C-H carbonylation of heterocyclic amines for the synthesis of lactam motifs has been developed. The reaction of 3-thiophene methylamines, 2-thiophene methylamines, and tryptamines with benzene-1,3,5-triyl triformate (TFBen) as the CO source provides a series of structurally diverse lactams in moderate to high yields with excellent regioselectivities.
Reference Key
ying2019siteselectivethe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Ying, Jun;Gao, Qian;Wu, Xiao-Feng;
Journal The Journal of organic chemistry
Year 2019
DOI
10.1021/acs.joc.9b02114
URL
Keywords
crystal structure ncn pincer organonickel phosphinimine

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