Synthesis, characterization, and crystal structures of organonickel(II) complexes coordinated to novel 1-bromo-2,6-bis{[(λ-phosphanylidene)imino]methyl}benzene NCN-pincer ligands.
Clicks: 361
ID: 58186
2019
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This
article has not been analysed, so there is no overall score —
reader engagement is measured and shown alongside.
Reader Engagement
Emerging Content
30.0
/100
361 views
43 readers
AI Quality Assessment
Not analyzed
Readership in this journal
EmergingRanked #14 of 63 articles by views in acta crystallographica section c, structural chemistry
Most read
Least read
Bar heights use a square-root scale.
Mint this article as an NFT
Not yet mintedCreate a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.
5
SUSD
one-off · no wallet required
Abstract
A novel family of four 1-bromo-2,6-bis{[(λ-phosphanylidene)imino]methyl}benzene ligands has been synthesized and characterized. The phosphiniminomethyl substituents are decorated with either three phenyl groups, two phenyl and one cyclohexyl group, one phenyl and two cyclohexyl groups, or three cyclohexyl groups. Each ligand was metallated using zero-valent nickel through an oxidative addition to form a family of organonickel(II) complexes, namely (2,6-bis{[(triphenyl-λ-phosphanylidene)imino]methyl}phenyl-κN,C,N')bromidonickel(II) dichloromethane hemisolvate, [NiBr(CHNP)]·0.5CHCl, (2,6-bis{[(cyclohexyldiphenyl-λ-phosphanylidene)imino]methyl}phenyl-κN,C,N')bromidonickel(II) diethyl ether hemisolvate, [NiBr(CHNP)]·0.5CHO, (2,6-bis{[(dicyclohexylphenyl-λ-phosphanylidene)imino]methyl}phenyl-κN,C,N')bromidonickel(II), [NiBr(CHNP)], and (2,6-bis{[(tricyclohexyl-λ-phosphanylidene)imino]methyl}phenyl-κN,C,N')bromidonickel(II), [NiBr(CHNP)]. This family of complexes represents a useful opportunity to investigate the impact of incrementally changing the steric characteristics of a complex on its structure and reactivity.
| Reference Key |
guillet2019synthesisacta
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | Guillet, Gary L;Pitts, Skyler L;Sheriff, Kirkland W;Rucker, Donna N;Rogers, Aaryn L; |
| Journal | acta crystallographica section c, structural chemistry |
| Year | 2019 |
| DOI |
10.1107/S2053229619012038
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.