Arylation of Click Triazoles with Diaryliodonium Salts.

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ID: 58119
2019
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Abstract
A robust, selective and highly efficient method for the preparation of 1,3,4-triaryl 1,2,3-triazolium salts has been developed. It features arylation of a click triazole with a diaryliodonium salt in the presence of a copper catalyst under neat conditions. The presence of pyridine functionality is tolerated, enabling the first access to key precursors of pyridyl-mesoionic carbene ligands. The method has been integrated into a one-pot protocol with a terminal alkyne, sodium azide, and diaryliodonium salt as staring compounds.
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virant2019arylationthe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Virant, Miha;Košmrlj, Janez;
Journal The Journal of organic chemistry
Year 2019
DOI
10.1021/acs.joc.9b02197
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