Fused polycyclic compounds via cycloaddition of 4-(1'-cyclohexenyl)-5-iodo-1,2,3-triazoles with 4-phenyl-1,2,4-triazoline-3,5-dione: the importance of a sacrificial iodide leaving group.

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ID: 57911
2013
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Abstract
4-(1'-Cyclohexenyl)-5-iodo-1,2,3-triazole and 4-phenyl-1,2,4-triazoline-3,5-dione undergo a formal Diels-Alder reaction, which following an S(N)2' solvolysis process to displace the iodo group affords a fused polycyclic compound.
Reference Key
michaels2013fusedthe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Michaels, Heather A;Simmons, J Tyler;Clark, Ronald J;Zhu, Lei;
Journal The Journal of organic chemistry
Year 2013
DOI
10.1021/jo400271j
URL
Keywords
annulation heterocycles synthetic methods reaction mechanisms rhodium

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