Fused polycyclic compounds via cycloaddition of 4-(1'-cyclohexenyl)-5-iodo-1,2,3-triazoles with 4-phenyl-1,2,4-triazoline-3,5-dione: the importance of a sacrificial iodide leaving group.
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2013
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Abstract
4-(1'-Cyclohexenyl)-5-iodo-1,2,3-triazole and 4-phenyl-1,2,4-triazoline-3,5-dione undergo a formal Diels-Alder reaction, which following an S(N)2' solvolysis process to displace the iodo group affords a fused polycyclic compound.
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| Authors | Michaels, Heather A;Simmons, J Tyler;Clark, Ronald J;Zhu, Lei; |
| Journal | The Journal of organic chemistry |
| Year | 2013 |
| DOI |
10.1021/jo400271j
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