Core-shell structured magnetic mesoporous carbon nanospheres derived from metal-polyphenol coordination polymer-coated Fe O and its application in the enrichment of phthalates from water samples.
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2019
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Abstract
In this work, core-shell structured magnetic mesoporous carbon nanospheres (MagC-TA) were fabricated from the carbonization of metal-polyphenol coordination polymer (MPCP)-coated Fe O nanoparticles. The preparation method is simple, fast, versatile, and easy to scale up. MagC-TA exhibit a high specific surface area, high superparamagnetism, and high adsorption efficiencies for phthalates (PAEs). Four PAEs were extracted from aqueous solutions by using MagC-TA via magnetic solid phase extraction. Subsequent analysis was performed by using high-performance liquid chromatography with ultraviolet detection. The analytical method has good linearity in the concentration range of 1.0-200 ng⋅mL for diethyl phthalate, diisobutyl phthalate, and dicyclohexyl phthalate, and 3.0-200 ng⋅mL for dipropyl phthalate. The limits of detection were in the range of 0.10-0.62 ng⋅mL . Compared with previous methods, this method has a lower detection limit, wider linearity range, and faster adsorption and desorption rates. The results indicate that MagC-TA are suitable for the enrichment of hydrophobic substances from aqueous solutions. This article is protected by copyright. All rights reserved.
| Reference Key |
xue2019coreshelljournal
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| Authors | Xue, Shan;Wang, Yiyu;Wu, Dan;Shen, Jiwei;Wei, Yinmao;Wang, Chaozhan; |
| Journal | journal of separation science |
| Year | 2019 |
| DOI |
10.1002/jssc.201900465
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