Towards fast-charging technologies in Li/Na storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors.
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2019
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Abstract
Since the discovery of the pseudocapacitive behavior in RuO2 by Sergio Trasatti and Giovanni Buzzanca in 1971, materials with pseudocapacitance have been regarded as promising candidates for high-power energy storage. Pseudocapacitance-involving energy storage is predominantly based on faradaic redox reactions, but at the same time the charge storage is not limited by solid-state ion diffusion. Besides the search for pseudocapacitive materials, their implementation into non-aqueous hybrid capacitors stands for the strategy to increase power density by a rational design of the battery structure. Composed of a battery-type anode and a capacitor-type cathode, such devices show great promise to integrate the merits of both batteries and capacitors. Today, the availability of fast-charging technologies is of fundamental importance for establishing electric vehicles on a mass scale. Therefore, from the perspective of materials and battery design, understanding the basics and the recent developments of pseudocapacitive materials and non-aqueous hybrid capacitors is of great importance. With this goal in mind, we introduce here the fundamentals of pseudocapacitance and non-aqueous hybrid capacitors. In addition, we provide an overview of the latest developments in this fast growing research field.
| Reference Key |
huang2019towardsnanoscale
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| Authors | Huang, Haijian;Niederberger, Markus; |
| Journal | Nanoscale |
| Year | 2019 |
| DOI |
10.1039/c9nr05732c
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