The Ingenious Synthesis of a Nitro-Free Insensitive High-Energy Material Featuring Face-to-Face and Edge-to-Face π-Interactions.

Clicks: 281
ID: 53907
2019
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #118 of 234 articles by views in Frontiers in chemistry

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 234 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Density, detonation property, and sensitivity may be the most valued features when evaluating an energetic material. By reasoning structure-property relationships, a nitro-free planar energetic material with high nitrogen and oxygen content, 7-hydroxy-difurazano[3,4-:3',4'-]furoxano[3″,4″-]azepine (), was synthesized using a unique and facile approach. The structure was fully characterized by IR and NMR spectra, elemental analysis, differential scanning calorimetry (DSC), and single-crystal X-ray diffraction. The expected properties of , including a high density of 1.92 g cm, high detonation velocity of 8,875 m s, and low mechanical sensitivities (impact sensitivity, 21 J and friction sensitivity, >360 N), confirm our strategy. Interestingly, the single-crystal structures of reveal expected face-to-face and edge-to-face π-interactions in the crystal stacking. The remarkable differences in crystal stacking of provide unequivocal evidence that face-to-face π-π interactions contribute significantly to closer assembly and higher density.
Reference Key
zhai2019thefrontiers Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Zhai, Lianjie;Bi, Fuqiang;Huo, Huan;Luo, Yifen;Li, Xiangzhi;Chen, Sanping;Wang, Bozhou;
Journal Frontiers in chemistry
Year 2019
DOI
10.3389/fchem.2019.00559
URL
Keywords
crystal structure energetic materials n-heterocycles detonation performances π-interactions

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.