Bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate
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ID: 53061
2018
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Abstract
The structure of bis(cobaltocenium) tetrachloridocobaltate(II) dichloromethane 1.2-solvate, [Co(C5H5)2]2[CoCl4]·1.2CH2Cl2, has been determined at 100 K. The title compound crystallizes in the space group P\overline{1} and is an example of an unusual Z′ = 5 structure. The asymmetric unit contains ten cobaltocenium ions, five tetrachloridocobaltate(II) ions and six molecules of dichloromethane, i.e. 5{[Cp2Co]2[CoCl4]}·6CH2Cl2. All the cobaltocenium ions are determined to be in the eclipsed conformation with respect to the cyclopentadienyl rings.
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| Authors | Shaw, Michael J.;Xu, Nan;Caveny, Ian E.;Abucayon, Erwin G.;Ramuglia, Anthony R.;Richter-Addo, George B.; |
| Journal | iucrdata |
| Year | 2018 |
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