Two-dimensional structure of poly[[[μ2-1,4-bis(pyridin-4-yl)butane]bis(μ4-pentanedioato)dicopper(II)] acetonitrile disolvate]

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ID: 53056
2017
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Abstract
In the title compound, {[Cu2(μ4-C5H6O4)2(μ2-C14H16N2)]·2CH3CN}n, the Cu2 dinuclear units are connected by glutartate ligands, forming one-dimensional double chains. These chains, are in turn bridged by 1,4-bis(pyridin-4-yl)butane ligands to form a two-dimensional layer structure parallel to (112). The carboxylate groups of the glutarate ligand bridge two copper(II) ions, forming a paddle-wheel-type Cu2(CO2)4 dinuclear secondary building unit. A crystallographic inversion centre is located midway between two CuII ions, with a Cu...Cu distance of 2.639 (3) Å. The coordination geometry of the unique CuII ion is slightly disorted square pyramidal, formed by four equatorial carboxylate O atoms and an axial pyridyl N atom.
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lee2017twodimensionaliucrdata Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Do Nam Lee, Youngmee Kim
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Journal iucrdata
Year 2017
DOI
DOI not found
URL
http://scripts.iucr.org/cgi-bin/paper?S2414314617014481
Keywords
crystallography

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