Attempted synthesis of a -metalated calix[4]arene.

Clicks: 190
ID: 50526
2019
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Ranked #40 of 50 articles by views in Beilstein journal of organic chemistry

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Abstract
An evidence for the formation of a rare -metalated inherently chiral calix[4]arene is described. Our strategy involved using a mesoionic carbene to direct C-H activation, but proved to form an unexpectedly unstable intermediate that was identified through high-resolution mass spectrometry. On route to our target, a new optimized method to mononitrocalix[4]arenes was developed, including optimized and high yielding transformations to azide and 1,2,3-triazole derivatives which may have application in other areas of research.
Reference Key
jurisch2019attemptedbeilstein Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Jurisch, Christopher D;Arnott, Gareth E;
Journal Beilstein journal of organic chemistry
Year 2019
DOI
10.3762/bjoc.15.195
URL
Keywords
calixarene inherent chirality mesoionic carbene mononitration ruthenacycle

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