MOFs-Derived Porous NiFeO Nano-Octahedrons with Hollow Interiors for an Excellent Toluene Gas Sensor.
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2019
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Abstract
Toluene is extensively used in many industrial products, which needs to be effectively detected by sensitive gas sensors even at low-ppm-level concentrations. Here, NiFeO nano-octahedrons were calcinated from NiFe-bimetallic metal-organic framework (MOFs) octahedrons synthesized by a facile refluxing method. The co-existence of p-Phthalic acid (PTA) and 3,3-diaminobenzidine (DAB) promotes the formation of smooth NiFe-bimetallic MOFs octahedrons. After subsequent thermal treatment, a big weight loss (about 85%) transformed NiFeO nanoparticles (30 nm) into NiFeO porous nano-octahedrons with hollow interiors. The NiFeO nano-octahedron based sensor exhibited excellent gas sensing properties for toluene with a nice stability, fast response, and recovery time (25 s/40 s to 100 ppm toluene), and a lower detection limitation (1 ppm) at 260 °C. The excellent toluene-sensing properties can not only be derived from the hollow interiors combined with porous nano-octahedrons to favor the diffusion of gas molecules, but also from the efficient catalytic activity of NiFeO nanoparticles.
| Reference Key |
zhang2019mofsderivednanomaterials
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| Authors | Zhang, Yanlin;Jia, Chaowei;Wang, Qiuyue;Kong, Quan;Chen, Gang;Guan, Hongtao;Dong, Chengjun; |
| Journal | Nanomaterials |
| Year | 2019 |
| DOI |
E1059
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