Poly[bis[μ-4-(4-carboxyphenoxy)benzoato](μ-4,4′-oxydibenzoato)bis[μ-3-(pyridin-4-yl)-5-(pyridin-3-yl)-1H-1,2,4-triazole]dicadmium(II)]
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ID: 4807
2016
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Abstract
Three kinds of bridging ligands, 4,4′-oxydibenzoate, 4-(4-carboxyphenoxy)benzoate and 3-(pyridin-4-yl)-5-(pyridin-3-yl)-1H-1,2,4-triazole, link the CdII cations to form the title polymeric complex, [Cd2(C14H8O5)(C14H9O5)2(C12H9N5)2]n, in which each CdII cation is in a distorted N2O5 pentagonal–bipyramidal coordination geometry. The 4,4′-oxydibenzoate dianion exhibits point group symmetry 2, with the central O atom located on a twofold rotation axis. Classical N—H...O, O—H...N hydrogen bonds and weak C—H...O hydrogen bonds link the complex molecules into a three-dimensional supramolecular architecture. A solvent-accessible void of 53 (2) Å3 is observed, but no solvent molecule could reasonably located there.
| Reference Key |
qi2016polybis44carboxyphenoxybenzoato44oxydibenzoatobis3pyridin4yl5pyridin3yl1h124triazoledicadmiumiiiucrdata
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|---|---|
| Authors | Qi, Xiao-Jin;Yuan, Bing-Nian;Zhang, Kang-Long; |
| Journal | iucrdata |
| Year | 2016 |
| DOI |
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| Keywords | Keywords not found |
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