Crystal structure of tetra-kis-[μ-3-carboxy-1-(1,2,4-triazol-4-yl)adamantane-κ:]tetra-fluoridodi-μ-oxido-dioxidodisilver(I)divanadium(V) tetra-hydrate.

Clicks: 365
ID: 4770
2019
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Abstract
The crystal structure of the title mol-ecular complex, [Ag{VOF}(CHNO)]·4HO, supported by the heterofunctional ligand [1-(1,2,4-triazol-4-yl)-3-carb-oxy-adamantane] is reported. Four 1,2,4-triazole groups of the ligand link two Ag atoms, as well as Ag and V centres, forming the heterobimetallic coordination cluster {Ag(VOF)()}. V exists as a vanadium oxofluoride anion and possesses a distorted trigonal-bipyramidal coordination environment [VOFN]. A carb-oxy-lic acid functional group of the ligand stays in a neutral form and is involved in hydrogen bonding with solvent water mol-ecules and VOF ions of adjacent mol-ecules. The extended hydrogen-bonding network is responsible for the crystal packing in the structure.
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senchyk2019crystalacta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Senchyk, Ganna A;Lysenko, Andrey B;Rusanov, Eduard B;Domasevitch, Kostiantyn V;
Journal acta crystallographica section e: crystallographic communications
Year 2019
DOI
10.1107/S2056989019006844
URL
Keywords Keywords not found

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