Nickel-Catalyzed Double Dehydrogenative Coupling of Secondary Alcohols and β-Amino Alcohols to Access Substituted Pyrroles.

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ID: 47438
2019
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Abstract
Herein, we demonstrated the first nickel-catalyzed double dehydrogenative condensation of secondary alcohols and β-amino alcohols in one-pot operation to the pyrrole derivatives. A series of 2,5 and 2,3,5-substituted pyrroles were obtained in up to 83% yield, releasing water and hydrogen gas as by-products. Initial mechanistic studies including defined Ni-catalysts, deuterium labeling experiments, quantitative determination of hydrogen gas evaluation and detection of water generation in the reaction mixture were performed.
Reference Key
alanthadka2019nickelcatalyzedthe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Alanthadka, Anitha;Bera, Sourajit;Vellakkaran, Mari;Banerjee, Debasis;
Journal The Journal of organic chemistry
Year 2019
DOI
10.1021/acs.joc.9b01819
URL
Keywords
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