2,6-Dichloro-9-thiabicyclo[3.3.1]nonane: Multigram Display of Azide and Cyanide Components on a Versatile Scaffold

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ID: 4726
1970
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Abstract
2,6-Dichloro-9-thiabicyclo[3.3.1]nonane, easily available by an improved condensation of sulfur dichloride, sulfuryl chloride, and 1,5-cyclooctadiene, is a well- behaved scaffold for the nucleophilic substitution of azides and cyanides via neighboring- group participation by the sulfur atom. The products are isolated in high yields with purity >95% by simple extraction and washing protocols.
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david197026dichloro9thiabicyclo331nonanemolecules Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors David Díaz Díaz;Antonella Converso;K. Barry Sharpless;M. G. Finn;Díaz, David Díaz;Converso, Antonella;Sharpless, K. Barry;Finn, M. G. and
Journal molecules
Year 1970
DOI
10.3390/11040212
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Keywords Keywords not found

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